Why is phosphate dosing done in a boiler? - Quora
Silica measurements are required at this point, principally to confirm that the maximum level of silica permissible in the boiler is not exceeded. 9 – Boiler Drum Silica build-up is monitored inside the boiler drum. The silica concentration is distributed between the water and vapour phases in a boiler…
In a phosphate precipitation treatment program, the magnesium portion of the hardness contamination is precipitated preferentially as magnesium silicate. If silica is not present, the magnesium will precipitate as magnesium hydroxide. If insufficient boiler water alkalinity is being maintained, magnesium can combine with phosphate.
why trisodium phosphate dosing in boiler drum – CFBC Boiler Manufac…
Only drum boiler units using phosphate boiler water treatment are included in this study. Information on concentration and transport of chemical impurities and sodium phosphate around drum boiler cycles was collected and correlated with chemical composition of low pressure (LP) turbine deposits collected after the water and steam sampling.
Excessive steam impurity concentrations can also be caused by feedwater and boiler water chemistries that favor volatile species formation. Carryover of volatile silica can be problematic at pressures above 1000 psig (6.9 MPa). Vaporous silica carryover at a pH of 10.0 is 88% of that at a pH of 8.8.
Why is phosphate dosing done in a boiler? - Quora
Generally the Phosphate dozing is done in the drum of the boiler. it helps to convert the calcium hard salts to soft sludge. the sludge is higher in weight,so it comes to the bottom of the drum . then it is removed by CBD. this is one of the way
Trisodium Phosphate dosing is done in boiler drum which react with scale forming salts like calcium cloride,calcium sulphate. 3 cacl2 + 2 na3 po4 = ca3 (po4)2 +6 nacl the sludge collected in bottom header which can be removed by operating low points drain. phosphate dosing is done to prevent scale formation in boiler
The amount of silica vaporized with the steam can be determined by measurement of boiler water silica. The proper boiler water silica level necessary to maintain less than 0.02 ppm silica in the steam is shown in Figure 18-4. When soluble, the silica present in boiler feedwater does not influence the amount of silica present in the steam.
Sep 01, 2009 · An online Hach 5000 Phosphate Analyzer is also installed to monitor boiler drum condensate. "We want to keep phosphate around 5 to 10 ppb, depending on how many megawatts we have," Gagliano says.
May 05, 2015 · Silica from CW is another damaging factor as it deposits on turbine. Silica needs to be controlled at DM plant also. Silica needs to be controlled at DM plant also. The percentage of impurity allowed in boiler water/steam is function of boiler operating pressure, so, …
rium phosphate treatment (EPT) was used for boiler control. Sodium triphosphate with a small amount of sodium hydroxide is added to the steam drum. PO4 concentration and pH are ad-justed within the defined operating range for EPT. Continuous blowdown is normally con-trolled by pH and on rare occasions by the silica concentration.
Cheat Sheet - Reactions • Bicarbonate Break: Na 2 HCO 3 + HEAT Na 2 CO 3 + CO 2 + H 2 O • Developed Alkalinity: Na 2 CO 3 + HEAT + 2H 2 O 2NaOH + CO 2 + H 2 O • Brining Reactions: CaCl + Boiler Water CaSO 4 + CaSiO 3 • Phosphate Reactions: Ca 3 (PO 4) 2 Tricalcium Phosphate [Low Alk.] • Phosphate Reaction: Ca 10 (OH) 2 (PO 4) 6
silica found in the boiler. Should the concentration of silica in the drum become too high, then a 'blowdown' is initiated. This is the removal of contaminated water from the boiler. Adequate control of the blowdown is very important. If it is allowed to occur too often, it becomes expensive and inefficient. The silica monitoring in the boiler drum is one parameter
Mar 16, 2020 · Phosphate. Mono-, di- or trisodium phosphate and sodium polyphosphate can be added to treat boiler feedwater. Phosphate buffers the water to minimize pH fluctuation. It also precipitates calcium or magnesium into a soft deposit rather than a hard scale. Additionally, it helps to promote the protective layer on boiler metal surfaces.
Dec 22, 2016 · For example, in a 1000 psi boiler the recommended maximum drum water silica concentration is 2.3 ppm. In a 2,400 psi steam generator the recommended maximum is 0.22 ppm!
scaling, corrosion and general deposition in the boiler drums and boiler tubes. x Condensate treatment: Chemical treatment of steam condensate, applied either The reaction of sulfite with oxygen can be written as: 2SO 3-2 + O 2 = 2SO 4-2 (3-18) Above 430°F (350 psia) sulfite reacts with iron oxide: 3Fe 2O 3 + SO 3-2 = 2Fe 3O 4 + SO 4
Silica Monitoring TECHNICAL NOTE On Power Plant
Water tube boiler Multiple drum system low pressure (LP) medium pressure (MP) Silica 6 0 % Condensate 50 Basic Boiler Calculations. Calculate the feedwater composition (impurities) from make up and condensate analysis below Phosphate/Polymer Treatment • Reactions